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18-6 Nihon Shokubai develops catalyst for hydroxycarbonylation

Formic acid can be prepared through hydrogenation of CO2. The hydroxycarbonylation reaction of alkenes using formic acid has conventionally been catalyzed by a rhodium complex, Rh2Cl2(CO)4, and additives, triphenylphosphine (PPh3) and methyl iodide (CH3I), which have...

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