A high-performance iron catalyst for the complete conversion of polyester into chemical raw materials

https://pubs.acs.org/doi/10.1021/acssusresmgt.5c00447

https://www.jst.go.jp/pr/announce/20251114/index.html

A team at Tokyo Metropolitan University has developed an inexpensive, readily available, high-performance iron catalyst that can convert polyester into high-purity chemical raw materials almost 100% simply by mixing and heating it with alcohol.

For the quantitative chemical conversions of PET pellets, bottle waste, and textile waste, transesterification was done with alcohols using FeCl3amine catalyst systems. The activity increased by adding small amounts of amine (benzimidazole). The scaleup reactions also afforded corresponding analytically pure terephthalates [e.g. dimethyl terephthalate (DMT) as white crystalline materials].

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